Thereisagrowinginterestindeterminingmercury(Hg)levelsinthemarineenvironmentaswellasinfishforhumanconsumption.Methylmercury(MeHg)inparticularisthemosttoxicandbioaccumulati... There is a growing interest in determining mercury(Hg) levels in the marine environment as well as in fish for human consumption.
Methyl mercury(Me Hg)in particular is the most toxic and bioaccumulative form of mercury in food webs and it is the predominant chemical form making up 80%-90% of the total mercury present in fish muscle tissue.Hence,fish and
other organisms at the end of the food chain constitute the
major source of MeHg in the human . As outcome of this risk,MeHg has been classically monitored in fish, and methodologies for mercury speciaion have increased significantly since the early 1990s. Currently, microwave-assisted extraction (MAE) has provided an efficient alternative strategy to conventional techniques for solvent extraction of a large amount of organometals compounds.The analytical techniques most frequently applied for Hg speciation analysis involve GC(GasChromatography) , GC-CICP-MS(Gas Chromatography -CInductively Coupled Plasma Mass Spectrometry)
supercritical fluids chromatography (SFC),ion chromatograph(IC), HPLC-CCVAAS(High Performance Liqui
Chromatography-Cold Vapor Atomic Absorption Spectrometry) or ICP-MS systems .Several authors recommended a back-extraction of mercury species from organic solvents to cysteine or sodium thiosulphate aqueous solutions .Because MeHg is the most common organomercury compound in biological materials ,here we offer a new simple and cost-effective method to determine MeHg. Basically, this method combines the microwave assisted extraction followed by clean-up with cysteine acetate solution and MeHg quantification by a direct mercury analyzer (DMA).
有一种越来越感兴趣,在确定水星汞对海洋环境的水平以及鱼供人类使用。
甲基汞(我)在特定的汞的毒性,bioaccumulative汞的形态在食物链与它是主要的化学形式的化妆80%-90%总汞的鱼类肌肉组织存在于…因此,鱼,
其他的生物体的食物链的构成
MeHg的主要来源的人。作为结果,MeHg的风险已经古典监测鱼、和方法学的水银speciaion大大提高自上世纪90年代早期。目前,微波辅助萃取已经提供了有效的战略选择传统的技术为溶剂萃取的大量的organometals化合物Z频繁的分析技术应用为汞的形态分析涉及GC(GasChromatography),GC-CICP-MS(毛细管气相色谱法-CInductively耦合等离子质谱)。
超临界流体色谱法、离子色谱(IC),HPLC-CCVAAS(高性能液态
Chromatography-Cold蒸汽原子吸收光谱法)或icp - ms系统阐述了作者推荐back-extraction汞的物种从有机溶剂,半胱氨酸,或加强显影加入硫代硫酸钠水溶液,因为MeHg是Z常见的organomercury化合物在生物材料,在这里我们提供一个新的简单和高MeHg确定方法。基本上,这个方法结合了微波萃取,紧随其后的是清理和半胱氨酸醋酸溶液和MeHg量化直接水星分析仪(DMA)。