文档简介FluorescentFilmSensorforVapor-PhaseNitroaromaticExplosivesviaMonolayerAssemblyofOligo(diphenylsilane)onGlassPlateSurfacesGangHe,GuofangZhang,FengtingLu¨,andYuFang*Afluorescentfilmsensorwaspreparedbychemicalassemblyofoligo(diphenylsilane)sonaglassplatesurfaceandwasusedforthedetectionofnitroaromaticcompounds(NACs)invaporphase.Thisdesigncombinestheadvantagesoffluorescentfilmsbasedonsingle-layerchemistryandthesignalamplificationeffectofconjugatedpolymersandprovidesaneffectivewaytocreatenovelfluorescencesensingfilmsforNACsexplosives.Theadvantageshavebeendemonstratedexperimentallybythesupersensitiveresponseoftheabove-mentionedfilmtothepresenceoftraceamountsofNACsinvaporphase.Furtherexperimentsshowedthatthesensingprocessisreversible,andthecommonlyencounteredinterferingsubstanceshavenointerferencetotheprocess.Fluorescencelifetimemeasurementsrevealedthatthequenchingisstaticinnature.Thesupersensitiveresponse,andthereversibilityandinterferencefreeofthesensingprocess,makethefilmapromisingNACssensor.
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