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上海科学仪器有限公司 2018-09-10
文档简介pH-AmplifiedExponentialGrowthMultilayers:AFacileMethodtoDevelopHierarchicalMicro-andNanostructuredSurfacesJinhongFu,JianJi,LiyanShen,AlexanderKu¨ller,AxelRosenhahn,JiacongShen,andMichaelGrunze*Wereportadirectmethodtoamplifytheexponentialgrowthofmultilayerssignificantlybythealternatingdepositionofpolyethylenimine(PEI)athighpHandpoly(acrylicacid)(PAA)atlowpH.ThealternatingpHswitchesthedegreeofionizationofthepolyelectrolytesinthemultilayers,whichenhancesthediffusionofPEIintoandoutofthefilmandhenceincreasesthedepositedmasspercycle.ThesynergeticactionofthepH-tunablechargedensityanddiffusivityoftheweakpolyelectrolytesprovidesanewmethodfortheenhancedgrowthofmultilayerswithhierarchalmicroandnanostructuredsurfaces.
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