文档简介PolymerplatingonAZ31magnesiumalloysurfaceandfilmevaluationofcorrosionpropertyZhixinKang,JingSang,MingShao,YuanyuanLiThepolymericthinfilmwaspreparedonthesurfaceofAZ31magnesiumalloybypolymerplatingof6-dihexylamino-1,3,5-triazine-2,4-dithiolmonosodium(DHN)inordertomodifyitssurfacefeatureandtoimproveitsanti-corrosiveproperty.Cyclicvoltammetrywasusedtostudytheelectrochemicalreactionandfilmgrowthprocessofpoly(6-dihexylamino-1,3,5-triazine-2,4-dithiol)(PDH)film,andthereactionpeaksforfilmformationandgrowthwereaffirmed.Thepolymericfilmweightwasdeterminedbyelectronicbalanceanditsinsolublefractionintetrahydrofuranwasalsomeasured.Contactanglemeterwasappliedtotestthesurfacewettabilitywithdistilledwaterdropsatambienttemperature.Itwasfoundthatthepolymer-platedAZ31alloyshowedhydrophobicpropertywithitsdistilledwatercontactangleupto117.2.TheperformancepropertyofpolymericthinfilmformedonAZ31surfacewasstudiedbypotentiodynamicpolarizationandelectrochemicalimpedancespectroscopy(EIS)inthecorrosionsolutionof3.5%NaCl.Theelectrochemicalexperimentresultsshowedthatpolymer-platedthinfilmwithhydrophobicandinsulativecharacteristicscouldprovidesurfacemodificationandaneffectiveanti-corrosiveprotectiontomagnesiumalloysubstratecomparedtotheblankone.
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