There is a fair body of literature concerning the electroreduction of glucose. This has been reviewed by Fedoronko. He divided his review into the polarographic work and that done on solid electrodes. The polarographic studies form a cohere... There is a fair body of literature concerning the electroreduction of glucose. This has been reviewed by Fedoronko. He divided his review into the polarographic work and that done on solid electrodes. The polarographic studies form a coherent picture, in which the experimentally observed data, which take the form of a plateau, not diffusion controlled, are explained in terms of a rate-determining step of mutarotation from the cyclic (inactive) form of the sugar to the linear (electroactive) form. The process is known to be both acid and base catalyzed, and has been reviewed by Capon. It is generally assumed that no hydrogen evolution takes place in the polaro- graphic plateau region.
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